PFA介绍 :
氟塑料具有耐热、耐寒、耐候、耐药品、耐溶剂,绝缘性能及高频电性能优异.并具有不枯性、自润滑性、低磨擦系数等特点。聚四氟乙烯、全氟(乙烯—丙烯)共聚物(FEP)完全是由碳原子和氟原子组成的,而聚偏氟乙烯(PVDF)、聚氟乙烯(PVF)分子中还含有氢原子但熔融碱金属、氟、三氟氯化烃对它们有不同程度的影响。PCTFE、ETFE、PVDF等在氟塑料中耐药品性稍差,但比其他塑料的耐腐蚀性还是好得多。3.电性能氟塑料的电性能尤其是高频电性能是其他材料难以匹敌的。PTFE、FEP、PFA分子的极性很低,在很宽的温度、频率区间变化都很小、相对介电常数稳定、介电损耗很低,电绝缘性优异。其中PVDF还有特异的压电性和焦电性,可用来制造压电材料。4.机械性能 氟塑料分子中含氢、氯原子增加则其拉伸强度也有所提高。PTFE和PCTFE的脆化温度极低,显示出极好的低温性能。PTFE具有较低的摩擦系数和特异的自润滑性。但是PTFE又有自身磨耗大和冷流性等缺点。可采用填充各种填料以提高耐磨耗性,克服冷流性。不粘性氟塑料具有特异的不粘性。尤其象PTPE、FEP、PFA等分子中氟含量高,表面接触角非常大,使氟塑料制品表面上的液体成球状。不易与树脂粘接,故常用它制造炊具表面不粘徐层。6耐侯性 各品种的氟塑料都有优异的耐候性,即使在苛刻的温度下长期曝晒,其各种性能都没有变化. 7.憎水性氟塑料的吸水率低,尤以PTFE为甚。可利用它的憎水性制造透气不透水的复合织物和其他装备。
Teflon® PFA TE9725
Perfluoroalkoxy
DuPont Fluoropolymers
产品说明:
For inventory control purposes product name may be followed by an X.
Products labeled PFA TE9725 and PFA TE9725 X are e and all information in this document is applicable to both.
Typical Application
DuPont™ Teflon ® PFA TE9725 is an ideal resin for applications involving compounding and compression molding, as well as extruded tubing and other profiles for hose, electrical insulators, and sleeving; industrial film and products made from film; and injection or blow-molded articles re superior electrical, chemical, and thermal properties. Teflon ® PFA TE9725 offers a slightly lower melt flow rate than Teflon ® PFA TE9724, ultimately providing a higher degree of stress-crack resistance.
Description
DuPont™ Teflon ® PFA TE9725 is a general purpose fluoroplastic resin available as loosely compacted fluff. It is intended for use in special application processes in consultation with DuPont. Compared with other grades of Teflon ® PFA, its most unique features are a relatively low flow rate and properties that make it suitable for a variety of processes and demanding end uses, especially compounding and compression molding. Table 1 shows the typical property data for Teflon ® PFA TE9725.
Teflon ® PFA TE9725 is used when traditional extrusion and molding processes are required for producing products with the superior properties of a fluoroplastic resin. Compared to other thermoplastics, the high melt strength and thermal stability of Teflon ® PFA TE9725 can be used to improve processing rates. Compared with other thermoplastics, Teflon ® PFA TE9725 provides a superior balance and level of end-use properties at high service temperatures. Teflon ® PFA TE9725 combines the processing ease of conventional thermoplastics with many properties similar to those of polytetrafluoroethylene.
Properly processed products made from neat Teflon ® PFA TE9725 resin provide the superior properties characteristic of fluoroplastic resins: chemical inertness, exceptional dielectric properties, heat resistance, toughness and flexibility, low coefficient of friction, non-stick characteristics, negligible moisture absorption, low flammability, performance at temperature extremes and excellent weather resistance.
In a flame situation, products of Teflon ® PFA TE9725 resist ignition and do not promote flame spread. When ignited by flame from other sources, their contribution of heat is very small and dded at a slow rate with very little smoke.
Teflon ® PFA TE9725 meets the re of ASTM D3307, Type II
物性信息:
基本信息 | |
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特性 |
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用途 |
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形式 |
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加工方法 |
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物理性能 | 额定值 | 单位制 | 测试方法 |
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比重 | 2.14 | g/cm³ | ASTM D792 |
熔流率(熔体流动速率) (372°C/5.0 kg) | 1.7 | g/10 min | ASTM D3307, ISO 12086 |
吸水率 (24 hr) | < 0.030 | % | ASTM D570 |
硬度 | 额定值 | 单位制 | 测试方法 |
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肖氏硬度 (邵氏 D) | 55 | ASTM D2240, ISO 868 |
机械性能 | 额定值 | 单位制 | 测试方法 |
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抗张强度 (23°C) | 26.0 | MPa | ASTM D3307, ISO 12086 |
伸长率 (断裂, 23°C) | 300 | % | ASTM D3307, ISO 12086 |
弯曲模量 (23°C) | 625 | MPa | ASTM D790, ISO 178 |
热性能 | 额定值 | 单位制 | 测试方法 |
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熔融温度 | 305 | °C | ASTM D4591 |
电气性能 | 额定值 | 单位制 | 测试方法 |
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体积电阻率 | 1.0E+18 | ohms·cm | ASTM D257, ISO 1325 |
介电强度 | |||
0.250 mm 1 | 80 | kV/mm | ASTM D149 |
0.250 mm | 80 | kV/mm | IEC 60243-1 |
介电常数 (1 MHz) | 2.03 | ASTM D150, IEC 60250 | |
耗散因数 (1 MHz) | < 2.0E-4 | ASTM D150, IEC 60250 |
可燃性 | 额定值 | 单位制 | 测试方法 |
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UL 阻燃等级 2 | V-0 | UL 94 | |
极限氧指数 | > 95 | % | ASTM D2863, ISO 4589-2 |
补充信息 | 额定值 | 单位制 | 测试方法 |
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MIT Folding Endurance 3(200.0 µm) | 5.0E+5 | Cycles | ASTM D2176 |
聚三氟氯乙烯则还含氯原子。氟塑料的优异性能是由碳原子与氟原子间的高结合能实现。聚四氟乙烯的主链骨架是碳原子,而周围完全由氟原子包围,故其各种性能高,而PFA、FEP、ETFE等品种由于侧基的影响,软化点低子PTFE,其他性能也有所变化。1.热性能氟塑料具有难燃性和优异的耐热性。PTFE和PFA的连续使用温度可达260℃,短期可在300℃下使用FEP的使用温度要比它们低60℃。PCTFE的可在120℃下使用。氟塑料如长期在高温下使用会引起结晶度变化,在制造设备衬里时尤须注意。2.耐药品性氟塑料具有卓越的耐药品性和耐溶剂性,尤其是PTFE、PFA、FEP等,酸、碱、溶剂对它们均无浸蚀但熔融碱金属、氟、三氟氯化烃对它们有不同程度的影响。